RESUMEN En general, los medios de comunicación y los boletines meteorológicos informan sobre el índice ultravioleta (UVI) para prevenir la sobreexposición al sol. Sin embargo, esta información no refleja el daño acumulado en la piel inducido por la cantidad total de UVR (radiación ultravioleta por sus siglas en inglés) acumulada en el tiempo, conocida como dosis eritematosa (ED). Este estudio analizó el UVI y el ED medidos a ±30 y ±60 minutos alrededor del mediodía solar (SN) en Arica, Norte de Chile. Los resultados muestran que SN ED superó la Mínima Dosis Eritematosa (MED por sus siglas en inglés) para todos los tipos de piel. Durante el verano, las exposiciones cortas a la luz solar de hasta 1 hora pueden resultar en una exposición solar hasta 10 veces mayor que el límite de seguridad ocupacional aceptable para la piel humana sin protección.

ABSTRACT News media and meteorological bulletins generally report on the ultraviolet index (UVI) to prevent overexposure to the sun. However, this information does not reflect the accumulated damage to the skin induced by the total amount of UVR (ultraviolet radiation) accumulated over time, known as erythemal dose (ED). This study analyzed the UVI and ED measured at ±30 and ±60 minutes around solar noon (SN) in Arica, North of Chile. The results show that SN ED exceeded the Minimum Erythema Dose (MED) for all the skin types. During the summer, shorts exposures to sunlight for up to 1 hour may result in sun exposure up to 10 times greater than the acceptable occupational safe limit for unprotected human skin.

Resumen La falta de cobertura es uno de los principales aceleradores de la degradación del suelo. Sin protección y expuesto a la lluvia, el suelo rompe las partículas, provocando el sellado de la superficie, dificultando la infiltración. Este estudio caracteriza el sellado superficial y la erosión hidráulica en Ultisoles de la Cuenca del Alto Ipanema. Se establecieron ocho parcelas de erosión bajo los tratamientos: suelo desnudo y suelo con mantillo de Brachiaria decumbens. Se simularon tres eventos de lluvia a intervalos de 24 horas, con una intensidad de 54,63 mmh-1. Después de cada simulación, se investigó la micromorfología de la superficie y la cantidad de suelo perdido. El uso de mantillo redujo la escorrentía en un 42% y la pérdida de suelo y la tasa de desagregación se redujo en un 70% en promedio. La infiltración se incrementó en un 242%. El mantillo fue eficaz para preservar la porosidad y la microestructura del suelo para el primer evento de lluvia simulado (0 h), pero no se observó en el segundo (24 h) y tercero (48 h) eventos de lluvia.

Abstract The lack of cover is one of the main accelerators of soil degradation. Without protection and exposed to rainfall, the soil breaks the particles, causing surface sealing, making infiltration difficult. This study characterizes surface sealing and hydraulic erosion in Ultisols of the Alto Ipanema Basin. Eight erosion plots were established under the treatments: bare soil and soil with Brachiaria decumbens mulch. Three rain events were simulated at 24-hour intervals, with an intensity of 54.63 mmh-1. After each simulation, the surface micromorphology and the amount of soil lost were investigated. The use of mulch reduced runoff by 42% and the loss of soil and the rate of disaggregation was reduced by 70% on average. Infiltration was increased by 242%. Mulch was effective in preserving soil porosity and microstructure for the first simulated rainfall event (0 h), but was not observed in the second (24 h) and third (48 h) rainfall events.

RESUMO OBJETIVOS: Avaliar a sazonalidade da 25(OH)vitamina D3 [25(OH)D3] e fatores associados em homens adultos saudáveis, que se exercitavam ao ar livre pelo menos 50 min duas vezes por semana, das 10 às 16h, em uma região subtropical. MÉTODOS: Sangue foi colhido no fim das estações para medir 25(OH)D3, por cromatografia líquida em tandem com espectroscopia de massas. A radiação ultravioleta foi estimada por radiômetro, calculando diariamente a resposta fotobiológica para sintetizar vitamina D na pele humana (D-VitD). RESULTADOS: A prevalência de 25(OH)D3 <20ng/mL foi sazonal (p=0.000): 8.7% (n=6/69), 1.5% (n=1/66), 0% (n= 0/64), e 21.7% (n=13/60), respectivamente, no final do inverno, primavera, verão e outono. A prevalência, ajustada para comparações múltiplas, foi maior no inverno do que no verão (p=0.026) e no outono do que na primavera (p=0.001) e verão (p=0.000). A 25(OH)D3 não se associou com o índice de massa corporal (p=0.207), gordura corporal (p=0.064) ou fototipo (p=0.485), na análise univariada. Associou-se à D-VitD nos 30 dias antes da coleta de sangue (p=0.000), ajustada para gordura corporal. Houve sazonalidade na prevalência de 25(OH)D3 <30ng/mL (p=0.000): 69.6% (n=48/69), 68.2% (n=45/66), 43.8% (n=28/64), e 88.4% (n=53/60), respectivamente, no inverno, primavera, verão e outono. CONCLUSÕES: Em uma região subtropical, houve sazonalidade na 25(OH)D3 em homens adultos, saudáveis, embora se exercitassem ao ar livre pelo menos 50 minutos duas vezes por semana, usando shorts e camiseta. 25(OH)D3 <20ng/mL foi 21.7% no outono e a D-vitD 30 dias antes da coleta do sangue foi o único fator associado de modo independente à 25(OH)D3.

SUMMARY OBJECTIVE: To evaluate seasonal variation of 25(OH)vitamin D [25(OH)D3] levels, and factors associated with it, in healthy adult men, who exercised outdoors for 50 min., at least twice a week, from 10AM to 4PM, in a Brazilian semitropical region. METHODS: Blood samples were collected at the end of each season for 25(OH)D3, measured by liquid chromatography with tandem mass spectrometry. Ultraviolet irradiation was estimated by radiometer, calculating the daily photobiological response to vitamin D synthesis in human skin (D-VitD). The prevalence of 25(OH)D3 <20ng/mL changed with the seasons (p=0.000): 8.7% (n=6/69), 1.5% (n=1/66), 0 (n=0/64), and 21.7% (n=13/60), respectively, at the end of winter, spring, summer, and autumn. The prevalence, adjusted for multiple comparisons, was higher in winter than summer (p=0.026), and in autumn than spring (p=0.001) and summer (p=0.000). There were no associations of 25(OH) D3 levels with BMI (p=0.207), body fat (p=0.064), and phototype (p=0.485), in univariate analysis. It was associated with D-VitD in the 30 days before blood sampling (p=0.000), after adjustment to body fat. The prevalence of 25(OH)D3 <30ng/mL varied seasonally (p=0.000): 69.6% (n=48/69), 68.2% (n=45/66), 43.8% (n=28/64), and 88.4% (n=53/60), respectively, in winter, spring, summer, and autumn. CONCLUSIONS: In a Brazilian subtropical region, a seasonal variation in 25(OH)D3 was observed in healthy adult males, although they spent at least 50 min outdoors twice a week, wearing shorts and T-shirts. 25(OH)D3 <20ng/mL was 21.7% in autumn; D-vitD 30 days prior to blood sampling was the only factor independently associated with 25(OH)D3 levels.

Resumo Os efeitos adversos das mudanças climáticas devem atingir o trabalho ao ar livre. Por esse motivo, o objetivo deste estudo é avaliar esses efeitos comparando-se a capacidade de trabalho na América do Sul entre clima presente (1979 a 2005) e o futuro (2071 - 2100). O estresse térmico foi estimado por meio do Environmental Stress Index (ESI), com base em variáveis atmosféricas provenientes das projeções climáticas do IPCC. Os resultados indicam que, mesmo em cenários climáticos favoráveis, a capacidade de trabalho pesado deve ser reduzida entre 25 a 50% no final do século XXI em praticamente toda a América do Sul, principalmente na região Amazônica, partes do norte e nordeste brasileiros, além de extensas regiões do Paraguai ao Suriname. Assim, cenários pessimistas, com intensificação do efeito estufa, podem implicar em falta de condições ambientais e físicas para trabalhos dessa natureza em horários atualmente comuns para a atividade laboral.

Abstract The adverse effects of climate change may affect work conducted outdoors. For this reason, this study seeks to evaluate these effects by comparing South American work capacity under climate conditions between 1979 and 2005, as well as expected future climate scenarios from 2071 to 2100. Thermal stress was estimated using the Environmental Stress Index (ESI), based on atmospheric variables for climate projections from the Intergovernmental Panel on Climate Change (IPCC). The results indicate that, even in favorable climate scenarios, outdoor manual labor capacity will be reduced by 25 to 50% by the end of the 21st century in basically all of South America, especially in the Amazonian regions, parts of the north and northeast of Brazil, and in vast regions from Paraguay to Suriname. There is an overall pessimistic outlook with respect to outdoor working conditions during common labor hours due to increases in the greenhouse effect.

Resumen Los efectos adversos del cambio climático deberían afectar el trabajo al aire libre. Por esta razón, el propósito de este estudio es evaluar estos efectos comparando la capacidad de trabajo en América del Sur entre el clima actual (1979 a 2005) y el futuro (2071 - 2100). El estrés térmico se estimó utilizando el Índice de Estrés Ambiental (ESI), basado en variables atmosféricas de las proyecciones climáticas del IPCC. Los resultados indican que, incluso en escenarios climáticos favorables, la capacidad de servicio pesado deberá reducirse entre un 25 y un 50% para fines del siglo XXI en prácticamente toda Sudamérica, especialmente en la región amazónica, partes del norte y noreste de Brasil, y desde extensas regiones desde Paraguay hasta el Surinam. Por lo tanto, los escenarios pesimistas, con la intensificación del efecto invernadero, pueden implicar una falta de condiciones ambientales y físicas para el trabajo de esta naturaleza en las horas de trabajo habituales actualmente.

RESUMO Pequenas variações de relevo influenciam na drenagem e no escoamento superficial, contribuindo para a formação de horizontes superficiais arenosos e subsuperficiais endurecidos (fragipãs e, ou, duripãs) em solos dos Tabuleiros Costeiros. Este trabalho investigou a pedogênese em área de Tabuleiros Costeiros com baixa amplitude altimétrica no Estado da Paraíba; secundariamente, buscamos contribuir para o aprimoramento do Sistema Brasileiro de Classificação de Solos (SiBCS). Quatro perfis de solos foram descritos e coletados para a realização das análises físicas e químicas de rotina, extrações de Fe, Si e Al por digestão sulfúrica, por ditionito-citrato-bicarbonato de sódio, por oxalato ácido de amônio e por pirofosfato de sódio, e as análises mineralógicas das frações areia e argila por difratometria de raios X. A densidade ótica do extrato de oxalato (ODOE) também foi determinada; os resultados obtidos foram estatisticamente avaliados utilizando o programa R. As variações do microrrelevo condicionando fluxos diferenciados de água, juntamente com a textura arenosa dos horizontes superficiais (A e E) e a menor relação areia grossa/areia fina no horizonte subsuperficial, parece favorecer o acúmulo de argila em profundidade nos Espodossolos desenvolvidos no ambiente dos Tabuleiros Costeiros. Para esses solos, o caráter argissólico em nível de subgrupo do SiBCS deveria ser incorporado. Além disso, fases mineralógicas amorfas e, ou, de baixa cristalinidade de Al têm importante participação na formação de horizontes fortemente cimentados (duripãs) dos Espodossolos. Finalmente, a ODOE mostrou-se eficiente como indicador de solos sob processo de podzolização e poderia ser utilizada como critério taxonômico para classificação de Espodossolos pelo SiBCS.

ABSTRACT Small variations of relief may change drainage and runoff and hence promote the formation of sandy surface horizons and hardened subsurface horizons (fragipans and/or duripans) in Coastal Tablelands soils. This study aimed to investigate the pedogenesis on Coastal Tablelands area with low range altimetry in Paraíba state; secondly, we also sought to contribute to the improvement of the Brazilian Soil Classification System (BSCS). Four soil profiles ware described and collected to be submitted to routine physical and chemical analysis, determination of Fe, Al and Si extracted by sulfuric acid digestion, sodium citrate-bicarbonate-dithionite and acid ammonium oxalate, sodium pyrophosphate, and mineralogical analysis in the sand and clay fractions by X-ray diffractometry. Optical density of the oxalate extract (ODOE) was also determined; the results were statistically evaluated using the R software. Microrelief variations conditioning differentiated water flows, along with the sandy texture of the surface horizons (A and E) and the lower coarse sand/fine sand ratio in the subsurface horizon, seem to promote clay accumulation in depth in the Spodosols developed on Coastal Tablelands environments. For this soils, the argilluvic (argissólico) character at the subgroup level of the BSCS should be incorporated. In addition, Al amorphous mineral phases and/or poorly crystalline play an important role in the formation of strongly cemented horizons (duripans) of the Spodosols, as also reported by other authors. Finally, the ODOE showed to be an efficient indicator of soils under podzolization process, being possible its use as a taxonomic criterion for classification of Spodosols by the BSCS.

SUMMARY Cushing’s syndrome (CS) is an uncommon condition that leads to high morbidity and mortality. The majority of endogenous CS is caused by excessive ACTH secretion, mainly due to a pituitary tumor – the so-called Cushing’s disease (CD) – followed by ectopic ACTH syndrome (EAS), an extra-pituitary tumor that produces ACTH; adrenal causes of CS are even rarer. Several methods are used to differentiate the two main etiologies: specific laboratory tests and imaging procedures, and bilateral inferior petrosal sinus sampling (BIPSS) for ACTH determination; however, identification of the source of ACTH overproduction is often a challenge. We report the case of a 28-year-old woman with clinical and laboratory findings consistent with ACTH-dependent CS. All tests were mostly definite, but several confounding factors provoked an extended delay in identifying the origin of ACTH secretion, prompting a worsening of her clinical condition, with difficulty controlling hyperglycemia, hypokalemia, and hypertension. During this period, clinical treatment was decisive, and measurement of morning salivary cortisol was a differential for monitoring cortisol levels. This report shows that clinical reasoning, experience and use of recent methods of nuclear medicine were decisive for the elucidation of the case.

ABSTRACT The micromorphology of deeply weathered soils (Ferralsols/ Latossolos ) from the Central Plateau of Brazil remains little studied, and its affiliation to different parent materials, poorly known. To clarify the processes of soil formation of these acric, gibbsitic, Fe-oxide rich Ferralsols, three lithotoposequences on local ultrabasic to basic intrusive rocks were studied. The influences of mixing and pedobioturbation are evident in all soils, and Ferralsols of the Central Plateau of Brazil are polygenetic, based on the coarse mineral composition, with ultrabasic and metapelitic rock contributions. The typical oxic microstructure with stable microaggregates encompasses a gibbsite/Fe rich micromass with random inclusions of charcoal, allochthonous quartz, Ti-magnetite, and perovskite grains. Shallow Cambisols ( Cambissolos ) on tuffites also display a similar “oxic” microstructure, but a much lower degree of weathering. These Cambisols possesses apatite, and mafic and pelitic minerals as residuals minerals grains, indicating the polygenetic colluvia mixture of different substrates. The common occurrence of perovskite (CaTiO3) as a residual grain in deep-weathered, acric Ferralsols on ultrabasic rocks, not yet reported in the literature, shows an unusual resistant Ca reserve in oxic soils, though nothing is known about its implications to soil fertility.

ABSTRACT Ferrimagnetic Fe-oxides are important soil components, which are present in most of the agricultural soils of Brazil. Distinction, origin, and assessment of the influence of these minerals on magnetism and geochemistry is a challenge for mineralogists. This study aimed to characterize mineralogically Fe-rich Rhodic Oxisols ( Latossolos Vermelhos ) originating from several mafic rocks in Brazil, and assess the implications on their magnetic and geochemical properties. We present results on magnetic measurements, chemical dissolutions, X-ray diffractometry, Rietveld refinement, Raman, and Mössbauer spectroscopies of Fe-rich Rhodic Oxisols originating from several mafic rocks. They show that magnetite is inherited from the parent material, and its oxidation leads to the formation of maghemite. In the coarse fractions (sand and silt), magnetite and maghemite coexist and are interstratified with hematite, confirmed by Raman spectroscopy. This limited the distinction between magnetite and maghemite by Mössbauer spectroscopy. Maghemite represents the only ferrimagnetic Fe oxide in the clay fraction. The influence of both ferrimagnetic minerals, magnetite and maghemite, on magnetic susceptibility and total content of trace elements is determined by the pedogenic development, even among highly weathered soils. In general, the coarse fractions contribute with most of the total trace element contents, while the clay fraction contributes to trace elements availability and magnetic susceptibility of soils.

ABSTRACT On the southern coast of Pernambuco State (PE), Brazil, lithotypes of the Cabo Basin (volcanic and sedimentary rocks), in association with the relief, allow the determination of the dynamics of the formation of Nitossolos Háplicos (Nitisols), including those with high levels of exchangeable aluminum. The objective of this study was to evaluate the influence of lithological diversity (basalt and sedimentary siliciclastic rocks) on the morphological, physical, chemical, and mineralogical properties of Nitossolos Háplicos along a slope (P1-summit, P2-backslope, P3-footslope) on the southern coast of PE, in order to consider its genesis and the relation of soil properties to adjacent environments and to evaluate its framing within the Brazilian Soil Classification System (SiBCS). The interaction of lithology/soil permeability and climate indicate significant differences in the mineralogical composition and dynamics of soil chemical elements. The profiles P1 and P2 are subject to monosialitization, ferralitization, and alitization processes. All profiles showed high Fe contents (ferric soils) and clay fractions, consisting primarily of kaolinite, goethite, hematite, and gibbsite, as well as quartz and feldspar in the sand and silt fractions. However, smectite minerals (P3) are probably inherited from the sedimentary source material. In the conglomerate samples, under P3, biotite, muscovite, and plagioclase were identified. Allytic characteristics (P3) are probably associated with the weathering of aluminous smectite minerals. These properties distinguish these soils from adjacent Nitossolos and other Nitossolos in Brazil. For the classification of soils according to SiBCS, considering the high levels of Fe and Al, Nitossolo Háplico distroférrico (P1 and P2) and Nitossolo Háplico alitiférrico (P3) are suggested, and according to the World Reference Base of Soils (WRB), the soils are classified as Ferritic Nitisols.

ABSTRACT: Fe-rich Oxisols on mafic rocks in Brazil generally have high magnetic susceptibility with high contents of some trace elements. These are taxonomically similar soils; however, differences in magnetic and geochemical properties may affect agricultural or environmental usability and subsequent management. This study investigated the pedogenesis of Fe-rich Oxisols from various parent materials and evaluated the lithogenetic influence on magnetic susceptibility and trace elements contents. Soil samples were collected from Bw horizons in 13 Rhodic Oxisols and a Typic Oxisol developed from several parent materials in Minas Gerais State, Brazil. Soils were analyzed by X-ray diffractometry (XRD) and magnetometry. Soil chemical analyses consisted of sulfuric and total (tri-acid) digestions and selective Fe oxides dissolutions and statistical correlations were determined. Fe-rich Oxisols presented a typical mineralogical composition of highly weathered soils with structural stability. The results confirm the difficulty to identify accurately magnetic minerals in different grain sizes using XRD. However, coarse fractions still exert dominant influence on the magnetic properties of the Fe-rich Rhodic Oxisols. In addition, coarse fractions probably contribute to the enrichment of superparamagnetic particles for the clay fraction. Although highly weathered, Fe-rich Oxisols may have their geochemical attributes still controlled by the parent material, where trace elements seem to be correlated with the magnetic minerals in the coarse fractions. Thus, the natural replacement of some trace elements from soil-solution equilibrium reactions during plant development could be more effective in soils with higher magnetic particles concentrations in the coarse fractions.

Resumo Este estudo tem como objetivo validar e analisar um conjunto de medidas de radiação solar ultravioleta (RUV) coletadas em seis localidades do Peru, cujas altitudes variam do nível do mar a 4479 m. Esta análise envolveu a avaliação do índice ultravioleta (IUV) e das doses eritematosas diárias (D-Er). Para tanto, as séries foram comparadas com simulações do modelo de transferência radiativa TUV e amostras de RUV coletadas sob condições de céu claro. As equações de regressão apontaram coeficientes de determinação elevados (R2 > 0,91), com alta significância estatística (p < 0,0001). Resultados mostraram que o recorde de IUV observado no Peru foi 23,5, registrado em Marcapomacocha (4479 m). Em relação às D-Er, destaca-se Arequipa com média de 7,9 kJm-2 diários (± 1,3 kJm-2), no verão. A D-Er recorde foi observada em Cajamarca no outono, com valor de 14,3 kJm-2. As doses diárias elevadas e o grande número de episódios de IUV muito altos e extremos evidenciam risco do desenvolvimento de doenças de pele relacionadas à exposição ao Sol, tal como o câncer de pele (CP). Por essa razão, este estudo fornece novos conhecimentos acerca da distribuição espaço-temporal da RUV no Peru, produzindo subsídios para políticas públicas de fotoproteção naquele país.

Abstract We evaluate a set of ultraviolet solar radiation (UVR) measurements collected in six locations in Peru: Ica, Tacna, Moquegua, Arequipa, Cajamarca and Marcapomacocha, whose altitudes vary from sea level to 4479 m. The analysis involved the validation and analysis of the ultraviolet index (UVI) and the daily erythemal doses (D-Er). Clear-sky filtered data were compared with numerical simulations provided by the Tropospheric Ultraviolet and Visible (TUV) radiation model in order to estimate numerical regression equations. These equations showed high determination coefficients (R2 > 0.91) statistical significance (p < 0.0001). Results show that the maximum UVI observed in Peru was 23.5 in Marcapomacocha (4479 m above sea level). Regarding D-Er, the highest means were observed in summer at the city of Arequipa with daily averages closer than 7.9 kJm-2 (± 1.3 kJm-2). However, the highest daily dose was observed in Cajamarca in the fall, with 14.3 kJm-2. These large amounts of high D-Er and very high and extreme UVI episodes indicate an important risk to the development of solar-related skin diseases, as the skin cancers. Our analysis provides a new knowledge on the spatial and temporal UV distribution in Peru and an important tool to justify public policies for solar protection.

RESUMO Os Nitossolos dão suporte ao desenvolvimento agrícola e socioeconômico de muitos países subdesenvolvidos do mundo, incluindo o Brasil. Os Nitossolos brasileiros estão geralmente associados às rochas basálticas das regiões Sul e Sudeste. Entretanto, Nitossolos derivado de basalto também ocorrem na costa sul de Pernambuco, uma região em pleno desenvolvimento urbano, agrícola e industrial. Objetivando compreender as relações entre o clima e os atributos dos Nitossolos da costa sul de Pernambuco, foram realizadas descrições morfológicas, análises físicas e químicas, extrações seletivas de ferro e a determinação da mineralogia das frações areia, silte e argila de três perfis derivados de basalto ao longo de uma vertente. Os resultados demonstram que o clima da região implica em forte intemperização dos perfis, em grande perda de bases e favorece o processo de xantização, resultando na singular gênese de Nitossolos com matizes amarelados e caráter ácrico, fato que até o momento ainda não foi catalogado para esta ordem no sistema taxonômico brasileiro. Os resultados também demonstram a variação dos atributos físicos dos Nitossolos ao longo da vertente.

ABSTRACT Nitisols are livelihood sources of agricultural and socio-economic development in several underdeveloped countries worldwide, including Brazil. Brazilian Nitisols are usually associated with basaltic rocks found in the Southern and Southeastern regions of the country. However, Nitisols derived from basalt also occur on the southern coast of Pernambuco state, a region under full urban, agricultural, and industrial development. Aiming to understand the relationship between climate and attributes of Nitisols from the southern coast of Pernambuco, we performed morphological descriptions, physical and chemical analyzes, iron selective extraction, and soil mineralogy (sand, silt, and clay) for three basaltic soil profiles along a land slope. The results suggest a strong weathering of the profiles due to climate conditions, besides a great loss of basic cations and xanthization process, resulting in the natural genesis of acric Nitisols with yellowish coloration, which has not been yet cataloged for this soil order in the Brazilian taxonomic system. In addition, there is a variation for physical attributes of Nitisols along the slope.

ABSTRACT Archaeological Dark Earth (ADE) pedogenesis and pre-Columbian history are fundamental for understanding the biodiversity and pedodiversity of the Neotropical rainforest in the Amazon region. This study aimed to evaluate the morphological, physical, chemical, and mineralogical properties as well as NaOH-extractable organic matter [OM(NaOH)] in ADE and Mulatto Earth (ME) overlying volcanic rocks along a toposequence (four soil profiles) in western Amazonia, Brazil. The soil profiles show anthropic A horizons over an argic horizon (Bt) in the ADE (Humic, Pretic Luvisols) and Bi in the ME (Clayic, Dystric Cambisols). The soil-forming processes in all of the profiles are associated with organic matter accumulation, such as humification and melanization, besides the formation of organometallic complexes. Calcium, Mg, P, and organic carbon contents were higher in ADE compared to ME. High-activity clays are derived from parent volcanic material, distinguishing the soils studied from Amazonian soils (Tertiary Plateau, Terra Firme) and most Amazonian anthropic soils. The anthropic horizons generally have a large contribution from OM(NaOH), predominantly humin and humic acids associated with Ca, Mg, and poorly crystalline Al hydroxides. The results suggest that the anthropic driving-forces caused greater differences in pedogenesis than the soil location in the landscape.

ABSTRACT Weathering and pedogenesis have been studied for a wide range of rocks and climates around the world. However, the eruption of rhyolitic magmas is a rare geological event, which leads to few studies associated with the rhyolite-soil-landscape relationship. In this context, this study evaluated the influence of rhyolite weathering on the properties of soils along a slope in an Atlantic Forest environment in the state of Pernambuco, northeastern Brazil. Four weathering profiles derived from rhyolites were classified and sampled for chemical, physical, mineralogical, micromorphological, differential thermal, and thermogravimetric analyses. The chemical properties reflect the original rock rich in felsic minerals, poor in bases, and the types of clay minerals. The clay fraction of the profiles consists mainly of 1:1 phyllosilicates and oxides, indicating intermediate weathering. However, variations in the degree of structure weathering were evidenced by the presence of partially preserved fragments of the original rock in the sand fraction of the soils. The tropical humid climate of the region influenced conversion of hematite to goethite through the xanthization process, and the subsurface drainage deficiency allowed the formation of halloysite in the lowest position of the landscape. Because it is an acid rock with an aphanitic texture and porphyritic relative size of crystals, rhyolite weathering resulted in the formation of dystrophic soils, with predominance of quartz in the silt fraction. From the top to the lower third of the slope, a Haplic Cambisol, an Abruptic Lixisol, and two Haplic Lixisols were formed.

ABSTRACT Despite the considerable amount of information on the mineralogical characteristics of pedogenic Fe oxides in Brazilian soils, there are few studies on Fe-rich soils developed from mafic rocks with taxonomic identities at lower categorical levels. This study evaluated the mineralogical characteristics of pedogenic Fe oxides in B horizons (Bw) of Fe-rich Oxisols developed from several mafic rocks in the state of Minas Gerais, Brazil. The Bw horizons were sampled at a 0.8-1.0 m depth in 13 Ferric and Perferric Rhodic Oxisols along with a Mesoferric Typic Oxisol originating from basalt, gabbro, tuffite, amphibolite and itabirite in Minas Gerais. The selected soils have taxonomic identities up to the fourth categorical level of the Brazilian System of Soil Classification. In the laboratory, the following analyses were made: a) powder X ray diffraction (XRD) of the clay fraction before and after selective concentration of Fe oxides by silicate alkaline dissolution (5 mol L-1 NaOH); b) selective chemical dissolution of the clay fraction by citrate-bicarbonate-dithionite (CBD), acid ammonium oxalate (AAO), and sulfuric acid (H2SO4 1.8 mol L-1); c) quantitative estimation of minerals in the clay fraction through allocation of phases from the XRD patterns, magnetic susceptibility of the clay fraction, and quantification of elements after sulfuric acid digestion (H2SO4 1:1) of the air-dried fine earth and treatment of the clay fraction with CBD; and d) estimation of the mean crystal size (MCS), specific surface area (SSA), and isomorphic Al-substitution (IS) of hematite, goethite, and maghemite from the XRD patterns obtained from concentrates of Fe oxides. The results showed that estimation of Fe content of maghemite by selective dissolution with 1.8 mol L-1 H2SO4 may not be accurate enough to realistically reflect the maghemite contents in the soil sample. The Al content extracted may also be influenced by other minerals that are sources of this element. Hematite crystals were predominantly placoid in shape in all Rhodic Oxisols and had smaller SSA compared to goethite, which showed both isodimensional and asymmetric habit. Higher crystallinity of maghemite and the IS values generally lower than those of hematite and goethite suggest that in well-drained soils derived from mafic rocks, the IS phenomenon in maghemites seems to result from pedogenetic advancement after its formation from magnetite oxidation.